848. Neue Versuche mit Spiropyran: Photometrie, NMR-Spektroskopie und On-Water-Synthese
Marcel Emmert, Jordan Karg, Katja Flora Weirauch, Chemkon, (2026), 10.1002/ckon.70012
Kinetics is often considered challenging due to its theoretical and mathematical complexity. Consequently, there is a need for kinetic experiments that are appropriate for chemistry classes. This article presents such experiments using a spiropyran dye and its isomeric merocyanine form. The decolorization reaction of merocyanine to the spiropyran isomer can be analyzed using photometry or nuclear magnetic resonance (NMR) spectroscopy. Photometry is well-suited for determining fundamental kinetic parameters, including the Arrhenius activation energy. While photometry can be implemented in secondary school teaching, 1H NMR spectroscopy is more appropriate for undergraduate laboratory courses. The latter provides deeper insight into the equilibrium between the spiropyran isomers following UV excitation. Since spiropyran is expensive to purchase, a synthesis suitable for educational settings is also presented. The starting materials are inexpensive, and students can perform the synthesis due to its low hazard potential.